| Item type |
共通(1) |
| 公開日 |
2017-12-05 |
| タイトル |
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タイトル |
Heterogeneous catalase-like activity of gold(I)–cobalt(III) metallosupramolecular ionic crystals |
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言語 |
en |
| 作成者 |
山田, 美穂子
吉成, 信人
桑村, 直人
齋藤, 徹
岡田, 賢
Maddala, Sai Prakash
原野, 幸治
中村, 栄一
山神, 光平
山中, 恵介
| en |
Yamanaka, Keisuke
Ritsumeikan University
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| ja-Kana |
ヤマナカ, ケイスケ
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| ja |
山中, 恵介
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Search repository
関山, 明
末延, 知義
山田, 裕介
今野, 巧
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| 権利情報 |
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言語 |
en |
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権利情報 |
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. This journal is © The Royal Society of Chemistry 2017 |
| 内容記述 |
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内容記述タイプ |
Abstract |
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内容記述 |
Unique heterogeneous catalase-like activity was observed for metallosupramolecular ionic crystals [Au^I_4Co^III_2(dppe)_2(D-pen)_4]X_n ([1]X_n; dppe = 1,2-bis(diphenylphosphino)ethane; D-pen = D-penicillaminate; X_n = (Cl^-)_2, (ClO_4)_2, (NO_3^-)_2 or SO_4^2) consisting of Au^I_4Co^III^2 complex cations, [1]^2+, and inorganic anions, X^- or X^2-. Treatment of the ionic crystals with an aqueous H_2O_2 solution led to considerable O_2 evolution with a high turnover frequency of 1.4 10^5 h^-1 for the heterogeneous cobalt complexes, which was dependent on their size and shape as well as the arrangement of cationic and anionic species.... |
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言語 |
en |
| 内容記述 |
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内容記述タイプ |
Other |
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内容記述 |
This work was supported in part by CREST, JST. One of the authors (M. Yamada) acknowledges the Futaba Electronics Memorial Foundation. K. Yamagami and T. Saito were supported by the Program for Leading Graduate Schools "Interactive Materials Science Cadet Program". The synchrotron radiation experiments were performed at the BL02B2 of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI) (Proposal No. 2015B1241). The soft XAS study was supported by the Project for Creation of Research Platforms and Sharing of Advanced Research Infrastructure, Japan (Proposal No. R1511). |
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言語 |
en |
| 出版者 |
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出版者 |
Royal Society of Chemistry |
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言語 |
en |
| 言語 |
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言語 |
eng |
| 記事種別等 |
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内容記述タイプ |
Other |
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内容記述 |
Edge Article |
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言語 |
en |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 出版タイプ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 識別子 |
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|
識別子 |
https://doi.org/10.1039/C6SC04993A |
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識別子タイプ |
DOI |
| 書誌情報 |
en : Chemical Science
巻 8,
号 4,
p. 2671-2676,
発行日 2017-01-16
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| 収録物識別子 |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
2041-6539 |
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