{"created":"2024-10-31T02:47:17.270981+00:00","id":2020505,"links":{},"metadata":{"_buckets":{"deposit":"012eefd0-a48d-48b3-9747-587f0a486c76"},"_deposit":{"created_by":7,"id":"2020505","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2020505"},"status":"published"},"_oai":{"id":"oai:ocu-omu.repo.nii.ac.jp:02020505","sets":["1623632832836:1721355153493"]},"author_link":[],"item_1617186331708":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Improved total synthesis of (±)-Tetragocarbone A","subitem_title_language":"ja"}]},"item_1617186419668":{"attribute_name":"作成者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Nishimura, Eiji","creatorNameLang":"en"},{"creatorName":"ニシムラ, エイジ","creatorNameLang":"ja-Kana"},{"creatorName":"西村, 栄治","creatorNameLang":"ja"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Yasuno, Yoko","creatorNameLang":"en"},{"creatorName":"ヤスノ, ヨウコ","creatorNameLang":"ja-Kana"},{"creatorName":"保野, 陽子","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1000040736500","nameIdentifierScheme":"KAKEN2","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000040736500"},{"nameIdentifier":"0000-0001-6725-8610","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0001-6725-8610"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Shinada, Tetsuro","creatorNameLang":"en"},{"creatorName":"シナダ, テツロウ","creatorNameLang":"ja-Kana"},{"creatorName":"品田, 哲郎","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1000030271513","nameIdentifierScheme":"KAKEN2","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000030271513"},{"nameIdentifier":"0000-0001-9145-1533","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0001-9145-1533"}]}]},"item_1617186499011":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"クリエイティブ・コモンズ　表示 - 非営利 - 改変禁止 4.0 国際 ","subitem_rights_language":"ja","subitem_rights_resource":"https://creativecommons.org/licenses/by-nc-nd/4.0/ "},{"subitem_rights":"Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International ","subitem_rights_language":"en","subitem_rights_resource":"https://creativecommons.org/licenses/by-nc-nd/4.0/ "},{"subitem_rights":"© 2018 Elsevier Ltd. This is the accepted manuscript version. The article has been published in final form at https://doi.org/10.1016/j.tet.2018.04.024","subitem_rights_language":"en"}]},"item_1617186609386":{"attribute_name":"主題","attribute_value_mlt":[{"subitem_subject":"フロログルシノール","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"全合成","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Phloroglucinol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Desymmetrization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydroxyl-directing reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Total synthesis","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Stereoselective total synthesis of (±)-tetragocarbon A isolated from the propolis of an Australian stingless bee, Tetragonula carbonara, has been developed by focusing on the latent symmetry of 1. The requisite 1R*, 3R*, 6S* stereogenic centers were selectively installed by hydroxy group directing reactions including the late stage desymmetrization of the 1,3-diketone. The target natural product was successfully prepared in 12 steps from phloroglucinol on 300 mg.","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"We thank the JSPS KAKENHI (No. 15K12758 and 17H05448), the Osaka City University Strategic Research Grant for Young Researchers (2016 & 2017), and JGC-S Scholarship Foundation Research Grant for financial support.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_1617186783814":{"attribute_name":"識別子","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"https://doi.org/10.1016/j.tet.2018.04.024"}]},"item_1617186920753":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"0040-4020","subitem_source_identifier_type":"ISSN"}]},"item_1617187056579":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05-24","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"2668","bibliographicPageStart":"2664","bibliographicVolumeNumber":"74","bibliographic_titles":[{"bibliographic_title":"Tetrahedron","bibliographic_titleLang":"en"}]}]},"item_1617258105262":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.tet.2018.04.024","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"AA11539786","subitem_relation_type_select":"NCID"}}]},"item_1722232185104":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-01"}],"displaytype":"detail","filename":"00404020-74-21-2664.pdf","filesize":[{"value":"522.4 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"本文","objectType":"fulltext","url":"https://ocu-omu.repo.nii.ac.jp/record/2020505/files/00404020-74-21-2664.pdf"},"version_id":"31f1e9cd-586f-4343-a7cf-779aed65eba6"}]},"item_1722577087681":{"attribute_name":"記事種別等","attribute_value_mlt":[{"subitem_description":"Research Article","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1725590125188":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_title":"Improved total synthesis of (±)-Tetragocarbone A","item_type_id":"40002","owner":"7","path":["1721355153493"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2020-06-01"},"publish_date":"2020-06-01","publish_status":"0","recid":"2020505","relation_version_is_last":true,"title":["Improved total synthesis of (±)-Tetragocarbone A"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2024-10-31T02:47:26.042465+00:00"}