{"created":"2024-10-31T01:50:01.599990+00:00","id":2020138,"links":{},"metadata":{"_buckets":{"deposit":"a6557a7b-69fe-48a6-8751-0ea97868d9d6"},"_deposit":{"created_by":7,"id":"2020138","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2020138"},"status":"published"},"_oai":{"id":"oai:ocu-omu.repo.nii.ac.jp:02020138","sets":["1623632832836:1721355153493"]},"author_link":[],"item_1617186331708":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"作成者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Toya, Yuki","creatorNameLang":"en"},{"creatorName":"トヤ, ユキ","creatorNameLang":"ja-Kana"},{"creatorName":"戸谷, 有希","creatorNameLang":"ja"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Hayasaka, Kazumasa","creatorNameLang":"en"},{"creatorName":"ハヤサカ, カズマサ","creatorNameLang":"ja-Kana"},{"creatorName":"早坂, 和将","creatorNameLang":"ja"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Nakazawa, Hiroshi","creatorNameLang":"en"},{"creatorName":"ナカザワ, ヒロシ","creatorNameLang":"ja-Kana"},{"creatorName":"中沢, 浩","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1000000172297","nameIdentifierScheme":"KAKEN2","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000000172297"},{"nameIdentifier":"read0186682","nameIdentifierScheme":"RESEARCHMAP","nameIdentifierURI":"https://researchmap.jp/read0186682"}]}]},"item_1617186499011":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.7b00087 .","subitem_rights_language":"en"}]},"item_1617186609386":{"attribute_name":"主題","attribute_value_mlt":[{"subitem_subject":"ヒドロシリル化反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"鉄錯体触媒","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ピンサー配位子","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"イミノビピリジン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrosilylation reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"iron complex catalysis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"pincer ligand","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"iminobipyridine ","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"A series of NNN-pincer iron complexes bearing ketimine-type iminobipyridene (BPI) ligands were prepared. These iron complexes were effective catalysts for the hydrosilylation of olefins using primary, secondary, and tertiary silanes. The effect of the substituents on the imino carbon on the catalytic activity was examined, and it was found that the appropriate combination of the imino carbon and imino nitrogen substituents led to complexes with quite high catalytic activity: the turnover number achieved was up to 42000. These iron catalytic systems provide a low-cost and promising alternative to currently employed precious metal systems for the hydrosilylation of olefins.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_1617186643794":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_1617186783814":{"attribute_name":"識別子","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"https://doi.org/10.1021/acs.organomet.7b00087"}]},"item_1617186920753":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"ISSN"}]},"item_1617187056579":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-04-20","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"1735","bibliographicPageStart":"1727","bibliographicVolumeNumber":"36","bibliographic_titles":[{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_1617258105262":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.7b00087","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"AA10627775","subitem_relation_type_select":"NCID"}}]},"item_1722232185104":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-07"}],"displaytype":"detail","filename":"02767333-36-9-1727.pdf","filesize":[{"value":"366.2 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"本文","objectType":"fulltext","url":"https://ocu-omu.repo.nii.ac.jp/record/2020138/files/02767333-36-9-1727.pdf"},"version_id":"91993331-e68b-4bc8-adf4-248f4329d48b"}]},"item_1722577087681":{"attribute_name":"記事種別等","attribute_value_mlt":[{"subitem_description":"Article","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1725590125188":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_title":"Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands","item_type_id":"40002","owner":"7","path":["1721355153493"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-05-07"},"publish_date":"2018-05-07","publish_status":"0","recid":"2020138","relation_version_is_last":true,"title":["Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2024-10-31T01:50:11.140176+00:00"}