{"created":"2024-10-31T01:36:38.498779+00:00","id":2019998,"links":{},"metadata":{"_buckets":{"deposit":"9a7e98ee-a4f7-4396-b78c-c3b27a078a78"},"_deposit":{"created_by":7,"id":"2019998","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"2019998"},"status":"published"},"_oai":{"id":"oai:ocu-omu.repo.nii.ac.jp:02019998","sets":["1623632832836:1721355153493"]},"author_link":[],"item_1617186331708":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Black phosphorus synthesized by solvothermal reaction from red phosphorus and its catalytic activity for water splitting","subitem_title_language":"en"}]},"item_1617186419668":{"attribute_name":"作成者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University, Sakai Chemical Industry, Co., Ltd","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Ozawa, Akiyo","creatorNameLang":"en"},{"creatorName":"オザワ, アキヨ","creatorNameLang":"ja-Kana"},{"creatorName":"小澤, 晃代","creatorNameLang":"ja"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Yamamoto, Muneaki","creatorNameLang":"en"},{"creatorName":"ヤマモト, ムネアキ","creatorNameLang":"ja-Kana"},{"creatorName":"山本, 宗昭","creatorNameLang":"ja"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Tanabe, Tetsuo","creatorNameLang":"en"},{"creatorName":"タナベ, テツオ","creatorNameLang":"ja-Kana"},{"creatorName":"田邉, 哲朗","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1000000029331","nameIdentifierScheme":"KAKEN2","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000000029331"},{"nameIdentifier":"read0183897","nameIdentifierScheme":"RESEARCHMAP","nameIdentifierURI":"https://researchmap.jp/read0183897"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Kyoto University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Hosokawa, Saburo","creatorNameLang":"en"},{"creatorName":"ホソカワ, サブロウ","creatorNameLang":"ja-Kana"},{"creatorName":"細川, 三郎","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1000090456806","nameIdentifierScheme":"KAKEN2","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000090456806"},{"nameIdentifier":"0000-0003-1251-3543","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0003-1251-3543"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Osaka City University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Yoshida, Tomoko","creatorNameLang":"en"},{"creatorName":"ヨシダ, トモコ","creatorNameLang":"ja-Kana"},{"creatorName":"吉田, 朋子","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"1000090283415","nameIdentifierScheme":"KAKEN2","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000090283415"},{"nameIdentifier":"read0045961","nameIdentifierScheme":"RESEARCHMAP","nameIdentifierURI":"https://researchmap.jp/read0045961"}]}]},"item_1617186499011":{"attribute_name":"権利情報","attribute_value_mlt":[{"subitem_rights":"The following article has been accepted by Journal of Materials Chemistry A. The final, published version is available at https://doi.org/10.1039/C9TA13441G. Please cite only the published version.","subitem_rights_language":"en"}]},"item_1617186609386":{"attribute_name":"主題","attribute_value_mlt":[{"subitem_subject":"太陽光エネルギー","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"赤リン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"黒リン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"エチレンジアミン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ソルボサーマル法","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究グループは、太陽光エネルギーを利用し、水から水素を生成する際の触媒として機能する黒リンを溶液法で高収率かつ簡便に合成する手法を開発しました。黒リンはリンの同素体の1つで、太陽光の可視光領域の大部分を吸収できる材料として注目を集めていますが、産業上必要となる大量合成が困難であるという課題を抱えていました。今回、安全で無害な赤リンを出発原料として、溶液法にて高収率で黒リンの合成に成功し、大量合成への途が拓かれました。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"We have succeeded in synthesizing black phosphorus (BP) by a one-pot solvothermal reaction of red phosphorus (RP) and ethylenediamine (ED) used as a solvent. To examine the reaction mechanism, we have investigated the influence of the synthesis conditions on BP, and the valence of dissolved phosphorus in the solvent after the reaction. P^0 species and P^^3+ like species are very likely dissolved in ED as intermediates for BP production....","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"This study was supported by JSPS KAKENHI Grant Number JP16H06440 (Synthesis of Mixed Anion Compounds toward Novel Functionalities).","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry ","subitem_publisher_language":"en"}]},"item_1617186783814":{"attribute_name":"識別子","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"https://doi.org/10.1039/C9TA13441G"}]},"item_1617186920753":{"attribute_name":"収録物識別子","attribute_value_mlt":[{"subitem_source_identifier":"2050-7496","subitem_source_identifier_type":"ISSN"}]},"item_1617187056579":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-04-21","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"7376","bibliographicPageStart":"7368","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"Journal of Materials Chemistry A","bibliographic_titleLang":"en"}]}]},"item_1617258105262":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_b1a7d7d4d402bcce","subitem_version_type":"AO"}]},"item_1617353299429":{"attribute_name":"関連情報","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/C9TA13441G","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"AA12605026","subitem_relation_type_select":"NCID"}}]},"item_1722232185104":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-05-12"}],"displaytype":"detail","filename":"20507496-8-15-7368.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"本文","objectType":"fulltext","url":"https://ocu-omu.repo.nii.ac.jp/record/2019998/files/20507496-8-15-7368.pdf"},"version_id":"49423328-87b5-45d0-8928-a3553ec6f17f"}]},"item_1722577087681":{"attribute_name":"記事種別等","attribute_value_mlt":[{"subitem_description":"Paper","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1725590125188":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_title":"Black phosphorus synthesized by solvothermal reaction from red phosphorus and its catalytic activity for water splitting","item_type_id":"40002","owner":"7","path":["1721355153493"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-05-12"},"publish_date":"2021-05-12","publish_status":"0","recid":"2019998","relation_version_is_last":true,"title":["Black phosphorus synthesized by solvothermal reaction from red phosphorus and its catalytic activity for water splitting"],"weko_creator_id":"7","weko_shared_id":-1},"updated":"2024-10-31T01:36:47.905562+00:00"}