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reviewed version of the following article: Iridium-Catalyzed Aerobic Coupling of Salicylaldehydes with Alkynes: A Remarkable Switch of Oxacyclic Product. A European Journal. 24, 7852-7855., which has been published in final form at https://doi.org/10.1002/chem.201801245 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_1617186609386":{"attribute_name":"主題","attribute_value_mlt":[{"subitem_subject":"C-H活性化","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"脱水素化","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"イリジウム","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"annulation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"C-H activation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"dehydrogenation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"iridium","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"oxygen heterocycles","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_1617186626617":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The iridium(III)/copper(II)-catalyzed dehydrogenative coupling of salicylaldehydes with internal alkynes proceeds efficiently under atmospheric oxygen through aldehyde C–H bond cleavage and decarbonylation. A variety of benzofuran derivatives can be synthesized by the environmentally-benign procedure....","subitem_description_language":"en","subitem_description_type":"Abstract"},{"subitem_description":"This experimental work was supported by JSPS KAKENHI Grant Number JP16H01037 (in Precisely Designed Catalysts with Customized Scaffolding), JST (ACT-C), Nagase Science Technology Foundation, and Yamada Science Foundation to T.S. and JSPS KAKENHI JP 17H06092 (Grant-in-Aid for Specially Promoted Research) to M.M. The numerical calculations were carried out on the TSUBAME 3.0 supercomputer at the Tokyo Institute of Technology, Tokyo, Japan, and on the supercomputer at the Research Center for Computational Science, Okazaki, Japan. This computational work was supported by a JST CREST (Grant Number JPMJCR1522 to S.K.) and JSPS KAKENHI Grant Number JP17K17720 (Grant-in-Aid for Young Scientists (B)) to Y.H. 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